I don't see how changing the port resolves this, all that does is switch between non-ssl to ssl. Anyways SSL should always be preferred.
The right error would be a relay issue, very few ISP return this error due to spam/ddos and there are a few things that cause the problem but the most common is your IP does not match what the SMTP expects, normally the case when not using the mail providers internet.
There is no automatic search for SMTP, so when you use someone elses internet, it does not choose their SMTP server, it just continues to use what was set.
You can solve this by adding your credentials (same as your POP3/IMAP username and password) to your SMTP server, so that you are verified. I don't use outlook so can't say how you do this.
Changing your SMTP settings to the current ISP network you are using at the time will work too since you are on the same network (IP) that will allow you to use their SMTP. This would be annoying and if there is an automatic feature, this would help here.
Use the web based mail client, which has its own method of sending mail, probably still uses their SMTP server but it meets their requirements. Especially considering you had to log in to use it and its their server (IP) that is expected.
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